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Journal: Environmental Science. Nano
Article Title: Visualization of pore water colloids in intact soil using a new diffusive gradients in thin films (DGT)-based approach
doi: 10.1039/d5en01069a
Figure Lengend Snippet: FlFFF fractograms of the FYM pore water sample showing elemental signals (a–e) and the UV signal (f) as a function of colloid retention time ( T r ), which corresponds to increasing colloid size. Organic colloids (<5 nm) elute at T r < 300 s, while larger mineral colloids (5–450 nm) elute at T r > 300 s. The red line in (a) shows the molar Si/Al ratio of the mineral colloids, the dotted red line indicates the Si/Al ratio of the clay fraction isolated from the soil. In the largest size fraction ( T r > 3700 s), the Si/Al ratio (2.1), matches that of the isolated clay. The blue line in (b) shows the molar Fe/Al ratio of the mineral colloids, the dotted blue line the ratio of the isolated clay. The Fe/Al ratio in the mineral colloids is only slightly higher than in the isolated clay.
Article Snippet: The colloids in pore waters were characterised with
Techniques: Isolation